Isotropic and anisotropic collision-induced light scattering spectra of krypton gas simultaneously fitted by ground state interatomic potential - Université d'Angers
Article Dans Une Revue Journal of Quantitative Spectroscopy and Radiative Transfer Année : 2022

Isotropic and anisotropic collision-induced light scattering spectra of krypton gas simultaneously fitted by ground state interatomic potential

Jean-Luc Godet
M.S.A. El-Kader
  • Fonction : Auteur

Résumé

Isotropic and anisotropic binary collision-induced light scattering spectra of gaseous krypton obtained atroom temperature are analyzed in terms of different interatomic potentials, both reference and recent,and trace and anisotropy models of interaction-induced polarizability. The spectral intensities obtainednumerically at low frequencies are determined by bound and free transitions. At intermediate and highfrequencies, the spectra are sensitive to both the attractive part of the potential and to short-range valuesof the trace or anisotropy. An empirical interatomic potential for the krypton gas interaction is developedby simultaneously fitting the Barker et al. (BFW) and modified Tang-Toennies (MTT) potentials to ther-mophysical and transport properties over a wide temperature range. The quality of the present potentialswas checked by comparison between the calculated and experimental vibrational energy levels. The re-sults show that these are the most accurate potentials reported to date for this system, both for thereproduction of spectral line shapes and spectral moments.
Fichier principal
Vignette du fichier
S0022407322001868.pdf (1.28 Mo) Télécharger le fichier
Origine Fichiers produits par l'(les) auteur(s)

Dates et versions

hal-04085838 , version 1 (22-07-2024)

Licence

Identifiants

Citer

Jean-Luc Godet, M.S.A. El-Kader. Isotropic and anisotropic collision-induced light scattering spectra of krypton gas simultaneously fitted by ground state interatomic potential. Journal of Quantitative Spectroscopy and Radiative Transfer, 2022, 288, pp.108251. ⟨10.1016/j.jqsrt.2022.108251⟩. ⟨hal-04085838⟩

Collections

UNIV-ANGERS LPHIA
48 Consultations
8 Téléchargements

Altmetric

Partager

More