A versatile building block for EDOT or PEDOT functionalization - Archive ouverte HAL Accéder directement au contenu
Article Dans Une Revue New Journal of Chemistry Année : 2008

A versatile building block for EDOT or PEDOT functionalization

(1) , (1) , (1) , (1)
1
Mirela Balog
  • Fonction : Auteur
Houari Rayah
  • Fonction : Auteur
Franck Le Derf
  • Fonction : Auteur
Marc Sallé

Résumé

A functionalized ethylenedioxythiophene (EDOT) derivative bearing a highly nucleophilic thiolate group has been synthesized. The efficiency of this new building block as a precursor to a wide range of EDOT-based monomers is demonstrated by reaction with different electrophilic species or by oxidation to a disulfide dimer. The corresponding electropolymerized PEDOT-based films, incorporating various side arms, have been prepared. In addition, the possibility to functionalize preformed PEDOT films obtained from these monomers, by nucleophilic substitution under heterogeneous conditions, was also checked thanks to the introduction of a tetrathiafulvalene redox probe.

Domaines

Chimie

Dates et versions

hal-03027871 , version 1 (27-11-2020)

Identifiants

Citer

Mirela Balog, Houari Rayah, Franck Le Derf, Marc Sallé. A versatile building block for EDOT or PEDOT functionalization. New Journal of Chemistry, 2008, 32 (7), pp.1183 - 1188. ⟨10.1039/b715568a⟩. ⟨hal-03027871⟩
11 Consultations
0 Téléchargements

Altmetric

Partager

Gmail Facebook Twitter LinkedIn More