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Article Dans Une Revue Journal of Electroanalytical Chemistry Année : 2022

Use of phase angle in alternating voltammetry on redox self-assembled monolayers with intermolecular interactions

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Olivier Alévêque
Eric Levillain

Résumé

We present a methodology based on the study of the frequency dependence of the phase angle in Alternative Voltammetry to estimate the standard electrochemical rate constant for heterogeneous electron transfer reactions in the case of strong intermolecular interactions occur between the redox forms. This work is a follow-up to our previous study which was dedicated only to the study of peak currents.
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Dates et versions

hal-03884457 , version 1 (05-12-2022)

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Olivier Alévêque, Eric Levillain. Use of phase angle in alternating voltammetry on redox self-assembled monolayers with intermolecular interactions. Journal of Electroanalytical Chemistry, 2022, 925, pp.116914. ⟨10.1016/j.jelechem.2022.116914⟩. ⟨hal-03884457⟩
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