Use of phase angle in alternating voltammetry on redox self-assembled monolayers with intermolecular interactions
Résumé
We present a methodology based on the study of the frequency dependence of the phase angle in Alternative Voltammetry to estimate the standard electrochemical rate constant for heterogeneous electron transfer reactions in the case of strong intermolecular interactions occur between the redox forms.
This work is a follow-up to our previous study which was dedicated only to the study of peak currents.
Origine | Fichiers produits par l'(les) auteur(s) |
---|