Straightforward N -alkylation of diketopyrrolopyrroles through the Mitsunobu reaction with benzyl, α-branched, and chiral alcohols - Archive ouverte HAL Accéder directement au contenu
Article Dans Une Revue Chemical Communications Année : 2021

Straightforward N -alkylation of diketopyrrolopyrroles through the Mitsunobu reaction with benzyl, α-branched, and chiral alcohols

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Maurizio Mastropasqua Talamo
Flavia Pop
Narcis Avarvari

Résumé

The N-alkylation of diketopyrrolopyrroles (DPPs) represents a fundamental step to ensure solubility and further processability. Commonly used nucleophilic substitution in halogenated derivatives is replaced in this work by the Mitsunobu reaction affording unprecedented DPPs with α-branched and chiral chains.

Domaines

Chimie
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Dates et versions

hal-03452266 , version 1 (26-11-2021)

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Citer

Maurizio Mastropasqua Talamo, Flavia Pop, Narcis Avarvari. Straightforward N -alkylation of diketopyrrolopyrroles through the Mitsunobu reaction with benzyl, α-branched, and chiral alcohols. Chemical Communications, 2021, 57 (53), pp.6514-6517. ⟨10.1039/d1cc02472h⟩. ⟨hal-03452266⟩
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