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Article Dans Une Revue Materials Année : 2014

A Self-Assembled Electro-Active M8L4 Cage Based on Tetrathiafulvalene Ligands

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1
Sébastien Goeb
Sébastien Bivaud
  • Fonction : Auteur
Vincent Croué
  • Fonction : Auteur
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Vaishali Vajpayee
  • Fonction : Auteur
Magali Allain
Marc Sallé

Résumé

Two self-assembled redox-active cages are presented. They are obtained by coordination-driven self-assembly of a tetra-pyridile tetrathiafulvalene ligand with cis-M(dppf)(OTf)2 (M = Pd or Pt; dppf = 1,1′-bis(diphenylphosphino)ferrocene; OTf = trifluoromethane-sulfonate) complexes. Both species are fully characterized and are constituted of 12 electro-active subunits that can be reversibly oxidized.

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Chimie
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Dates et versions

hal-03347300 , version 1 (17-09-2021)

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Citer

Sébastien Goeb, Sébastien Bivaud, Vincent Croué, Vaishali Vajpayee, Magali Allain, et al.. A Self-Assembled Electro-Active M8L4 Cage Based on Tetrathiafulvalene Ligands. Materials, 2014, 7, pp.611-622. ⟨10.3390/ma7010611⟩. ⟨hal-03347300⟩
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