Rigid oligomers based on the combination of 3,6-dimethoxythieno[3,2-b]thiophene and 3,4-ethylenedioxythiophene - Archive ouverte HAL Accéder directement au contenu
Article Dans Une Revue Tetrahedron Letters Année : 2009

Rigid oligomers based on the combination of 3,6-dimethoxythieno[3,2-b]thiophene and 3,4-ethylenedioxythiophene

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1
Mathieu Turbiez
  • Fonction : Auteur
Noémie Hergué
  • Fonction : Auteur
Philippe Leriche
Pierre Frère

Résumé

New oligomers based on the combination of the 3,6-dimethoxythieno[3,2-b]thiophene and 3,4-ethylenedioxythiophene (EDOT) moieties have been prepared and studied by UV–vis spectroscopy and cyclic voltammetry. The use of the intrinsically rigid thienothiophene units in addition to the S⋯O intramolecular interactions leads to planar conformation of the conjugated chains. While the radical cations of oligomers end capped by n-hexyl chains show a tendency to the dimerization, those substituted by n-hexylsulfanyl chains present a high stability.

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Chimie
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Dates et versions

hal-03343424 , version 1 (14-09-2021)

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Citer

Mathieu Turbiez, Noémie Hergué, Philippe Leriche, Pierre Frère. Rigid oligomers based on the combination of 3,6-dimethoxythieno[3,2-b]thiophene and 3,4-ethylenedioxythiophene. Tetrahedron Letters, 2009, 50 (51), pp.7148 - 7151. ⟨10.1016/j.tetlet.2009.10.021⟩. ⟨hal-03343424⟩
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