Constructing Robust Channel Structures by Packing Metallacalixarenes: Reversible Single-Crystal-to-Single-Crystal Dehydration - Archive ouverte HAL Accéder directement au contenu
Article Dans Une Revue Journal of the American Chemical Society Année : 2009

Constructing Robust Channel Structures by Packing Metallacalixarenes: Reversible Single-Crystal-to-Single-Crystal Dehydration

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Cristian-D. Ene
  • Fonction : Auteur
Augustin-M. Madalan
  • Fonction : Auteur
Catalin Maxim
  • Fonction : Auteur
Bogdan Jurca
  • Fonction : Auteur
Narcis Avarvari
Marius Andruh

Résumé

The self-assembly process involving the dianion of trimesic acid (Htrim2−) and {Cu(tmen)}2+ templating cations (tmen = N,N,N′,N′-tetramethylethylenediamine) affords a new metallacalixarene, [Cu4(tmen)4(Htrim)4]·nH2O. The packing of the cyclic molecules in the crystal generates channels that are filled by water molecules. The dehydration−rehydration process of the crystals was found to be reversible.

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Chimie
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Dates et versions

hal-03343350 , version 1 (14-09-2021)

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Citer

Cristian-D. Ene, Augustin-M. Madalan, Catalin Maxim, Bogdan Jurca, Narcis Avarvari, et al.. Constructing Robust Channel Structures by Packing Metallacalixarenes: Reversible Single-Crystal-to-Single-Crystal Dehydration. Journal of the American Chemical Society, 2009, 131 (13), pp.4586 - 4587. ⟨10.1021/ja900416e⟩. ⟨hal-03343350⟩
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