<?xml version="1.0" encoding="utf-8"?>
<TEI xmlns="http://www.tei-c.org/ns/1.0" xmlns:xsi="http://www.w3.org/2001/XMLSchema-instance" xmlns:hal="http://hal.archives-ouvertes.fr/" xmlns:gml="http://www.opengis.net/gml/3.3/" xmlns:gmlce="http://www.opengis.net/gml/3.3/ce" version="1.1" xsi:schemaLocation="http://www.tei-c.org/ns/1.0 http://api.archives-ouvertes.fr/documents/aofr-sword.xsd">
  <teiHeader>
    <fileDesc>
      <titleStmt>
        <title>HAL TEI export of hal-02564569</title>
      </titleStmt>
      <publicationStmt>
        <distributor>CCSD</distributor>
        <availability status="restricted">
          <licence target="https://creativecommons.org/publicdomain/zero/1.0/">CC0 1.0 - Universal</licence>
        </availability>
        <date when="2026-04-29T10:05:51+02:00"/>
      </publicationStmt>
      <sourceDesc>
        <p part="N">HAL API Platform</p>
      </sourceDesc>
    </fileDesc>
  </teiHeader>
  <text>
    <body>
      <listBibl>
        <biblFull>
          <titleStmt>
            <title xml:lang="en">A M2L2 Redox-Active Metalla-Macrocycle Based on Electron-Rich 9-(1,3-Dithiol-2-ylidene)Fluorene</title>
            <author role="aut">
              <persName>
                <forename type="first">Serhii</forename>
                <surname>Krykun</surname>
              </persName>
              <idno type="halauthorid">1540885-0</idno>
              <affiliation ref="#struct-213131"/>
            </author>
            <author role="aut">
              <persName>
                <forename type="first">Magali</forename>
                <surname>Allain</surname>
              </persName>
              <email type="md5">497756c04db59a112b36cc9b5aa6b084</email>
              <email type="domain">univ-angers.fr</email>
              <idno type="idhal" notation="string">magali-allain</idno>
              <idno type="idhal" notation="numeric">182380</idno>
              <idno type="halauthorid" notation="string">29205-182380</idno>
              <idno type="ORCID">https://orcid.org/0000-0002-0893-6028</idno>
              <idno type="IDREF">https://www.idref.fr/250390272</idno>
              <idno type="VIAF">https://viaf.org/viaf/170160789887002682858</idno>
              <affiliation ref="#struct-213131"/>
            </author>
            <author role="aut">
              <persName>
                <forename type="first">Vincent</forename>
                <surname>Carré</surname>
              </persName>
              <email type="md5">825e36ffe94e6d48a1ad788d1ada0553</email>
              <email type="domain">univ-lorraine.fr</email>
              <idno type="idhal" notation="string">vincent-carre</idno>
              <idno type="idhal" notation="numeric">173675</idno>
              <idno type="halauthorid" notation="string">42357-173675</idno>
              <idno type="ORCID">https://orcid.org/0000-0002-0719-7366</idno>
              <idno type="IDREF">https://www.idref.fr/08161814X</idno>
              <affiliation ref="#struct-439404"/>
            </author>
            <author role="aut">
              <persName>
                <forename type="first">Frédéric</forename>
                <surname>Aubriet</surname>
              </persName>
              <email type="md5">2f9e6cd9200bbc781fdb5830bcbb4544</email>
              <email type="domain">univ-lorraine.fr</email>
              <idno type="idhal" notation="string">frederic-aubriet</idno>
              <idno type="idhal" notation="numeric">744659</idno>
              <idno type="halauthorid" notation="string">874320-744659</idno>
              <idno type="ORCID">https://orcid.org/0000-0003-2457-7974</idno>
              <idno type="IDREF">https://www.idref.fr/156247615</idno>
              <affiliation ref="#struct-439404"/>
            </author>
            <author role="aut">
              <persName>
                <forename type="first">Zoia</forename>
                <surname>Voitenko</surname>
              </persName>
              <idno type="halauthorid">1154877-0</idno>
              <affiliation ref="#struct-304384"/>
            </author>
            <author role="aut">
              <persName>
                <forename type="first">Sébastien</forename>
                <surname>Goeb</surname>
              </persName>
              <email type="md5">3a5b95f3d43ce9922484245a78c22792</email>
              <email type="domain">univ-angers.fr</email>
              <idno type="idhal" notation="string">sgoeb</idno>
              <idno type="idhal" notation="numeric">176197</idno>
              <idno type="halauthorid" notation="string">31859-176197</idno>
              <idno type="ORCID">https://orcid.org/0000-0003-2470-0768</idno>
              <idno type="IDREF">https://www.idref.fr/118654667</idno>
              <affiliation ref="#struct-213131"/>
            </author>
            <author role="aut">
              <persName>
                <forename type="first">Marc</forename>
                <surname>Sallé</surname>
              </persName>
              <email type="md5">c2c9a4bd6f3469d0a452e9b6e8627277</email>
              <email type="domain">univ-angers.fr</email>
              <idno type="idhal" notation="string">marc-salle</idno>
              <idno type="idhal" notation="numeric">183386</idno>
              <idno type="halauthorid" notation="string">28631-183386</idno>
              <idno type="ORCID">https://orcid.org/0000-0003-4601-6334</idno>
              <idno type="IDREF">https://www.idref.fr/09085697X</idno>
              <affiliation ref="#struct-213131"/>
            </author>
            <editor role="depositor">
              <persName>
                <forename>Okina</forename>
                <surname>Univ Angers</surname>
              </persName>
              <email type="md5">b5db9c104e451c4c3e7e86bba508166f</email>
              <email type="domain">contact.univ-angers.fr</email>
            </editor>
            <funder ref="#projanr-40813"/>
          </titleStmt>
          <editionStmt>
            <edition n="v1" type="current">
              <date type="whenSubmitted">2020-05-05 22:14:14</date>
              <date type="whenModified">2025-11-04 14:22:01</date>
              <date type="whenReleased">2020-05-06 10:22:28</date>
              <date type="whenProduced">2018</date>
              <date type="whenEndEmbargoed">2018-10-26</date>
              <ref type="file" target="https://univ-angers.hal.science/hal-02564569v1/document">
                <date notBefore="2018-10-26"/>
              </ref>
              <ref type="file" subtype="author" n="1" target="https://univ-angers.hal.science/hal-02564569v1/file/inorganics-06-00044.pdf" id="file-2564569-2430381">
                <date notBefore="2018-10-26"/>
              </ref>
              <ref type="externalLink" target="https://www.mdpi.com/2304-6740/6/2/44/pdf"/>
            </edition>
            <respStmt>
              <resp>contributor</resp>
              <name key="300611">
                <persName>
                  <forename>Okina</forename>
                  <surname>Univ Angers</surname>
                </persName>
                <email type="md5">b5db9c104e451c4c3e7e86bba508166f</email>
                <email type="domain">contact.univ-angers.fr</email>
              </name>
            </respStmt>
          </editionStmt>
          <publicationStmt>
            <distributor>CCSD</distributor>
            <idno type="halId">hal-02564569</idno>
            <idno type="halUri">https://univ-angers.hal.science/hal-02564569</idno>
            <idno type="halBibtex">krykun:hal-02564569</idno>
            <idno type="halRefHtml">&lt;i&gt;Inorganics&lt;/i&gt;, 2018, 6 (2), pp.44. &lt;a target="_blank" href="https://dx.doi.org/10.3390/inorganics6020044"&gt;&amp;#x27E8;10.3390/inorganics6020044&amp;#x27E9;&lt;/a&gt;</idno>
            <idno type="halRef">Inorganics, 2018, 6 (2), pp.44. &amp;#x27E8;10.3390/inorganics6020044&amp;#x27E9;</idno>
            <availability status="restricted">
              <licence target="https://creativecommons.org/licenses/by/4.0/">CC BY 4.0 - Attribution<ref corresp="#file-2564569-2430381"/></licence>
            </availability>
          </publicationStmt>
          <seriesStmt>
            <idno type="stamp" n="CNRS">CNRS - Centre national de la recherche scientifique</idno>
            <idno type="stamp" n="UNIV-ANGERS">Université d'Angers</idno>
            <idno type="stamp" n="UNIV-LORRAINE">Université de Lorraine</idno>
            <idno type="stamp" n="INC-CNRS">Institut de Chimie du CNRS</idno>
            <idno type="stamp" n="LCPA2MC-UL">LCP-A2MC - Laboratoire de Chimie et Physique - Approche Multi-échelle des Milieux Complexes</idno>
            <idno type="stamp" n="MOLTECH-ANJOU" corresp="UNIV-ANGERS">MOLTECH-Anjou</idno>
            <idno type="stamp" n="TEST-HALCNRS">Collection test HAL CNRS</idno>
            <idno type="stamp" n="ANR">ANR</idno>
            <idno type="stamp" n="TEST2-HALCNRS">TEST2-HALCNRS</idno>
            <idno type="stamp" n="LCPA2MC-EQ3">LCP-A2MC - Equipe Chimie durable et Environnement</idno>
            <idno type="stamp" n="CPM-UL">Pôle scientifique Chimie et Physique Moléculaire de l'Université de Lorraine</idno>
          </seriesStmt>
          <notesStmt>
            <note type="audience" n="2">International</note>
            <note type="popular" n="0">No</note>
            <note type="peer" n="1">Yes</note>
          </notesStmt>
          <sourceDesc>
            <biblStruct>
              <analytic>
                <title xml:lang="en">A M2L2 Redox-Active Metalla-Macrocycle Based on Electron-Rich 9-(1,3-Dithiol-2-ylidene)Fluorene</title>
                <author role="aut">
                  <persName>
                    <forename type="first">Serhii</forename>
                    <surname>Krykun</surname>
                  </persName>
                  <idno type="halauthorid">1540885-0</idno>
                  <affiliation ref="#struct-213131"/>
                </author>
                <author role="aut">
                  <persName>
                    <forename type="first">Magali</forename>
                    <surname>Allain</surname>
                  </persName>
                  <email type="md5">497756c04db59a112b36cc9b5aa6b084</email>
                  <email type="domain">univ-angers.fr</email>
                  <idno type="idhal" notation="string">magali-allain</idno>
                  <idno type="idhal" notation="numeric">182380</idno>
                  <idno type="halauthorid" notation="string">29205-182380</idno>
                  <idno type="ORCID">https://orcid.org/0000-0002-0893-6028</idno>
                  <idno type="IDREF">https://www.idref.fr/250390272</idno>
                  <idno type="VIAF">https://viaf.org/viaf/170160789887002682858</idno>
                  <affiliation ref="#struct-213131"/>
                </author>
                <author role="aut">
                  <persName>
                    <forename type="first">Vincent</forename>
                    <surname>Carré</surname>
                  </persName>
                  <email type="md5">825e36ffe94e6d48a1ad788d1ada0553</email>
                  <email type="domain">univ-lorraine.fr</email>
                  <idno type="idhal" notation="string">vincent-carre</idno>
                  <idno type="idhal" notation="numeric">173675</idno>
                  <idno type="halauthorid" notation="string">42357-173675</idno>
                  <idno type="ORCID">https://orcid.org/0000-0002-0719-7366</idno>
                  <idno type="IDREF">https://www.idref.fr/08161814X</idno>
                  <affiliation ref="#struct-439404"/>
                </author>
                <author role="aut">
                  <persName>
                    <forename type="first">Frédéric</forename>
                    <surname>Aubriet</surname>
                  </persName>
                  <email type="md5">2f9e6cd9200bbc781fdb5830bcbb4544</email>
                  <email type="domain">univ-lorraine.fr</email>
                  <idno type="idhal" notation="string">frederic-aubriet</idno>
                  <idno type="idhal" notation="numeric">744659</idno>
                  <idno type="halauthorid" notation="string">874320-744659</idno>
                  <idno type="ORCID">https://orcid.org/0000-0003-2457-7974</idno>
                  <idno type="IDREF">https://www.idref.fr/156247615</idno>
                  <affiliation ref="#struct-439404"/>
                </author>
                <author role="aut">
                  <persName>
                    <forename type="first">Zoia</forename>
                    <surname>Voitenko</surname>
                  </persName>
                  <idno type="halauthorid">1154877-0</idno>
                  <affiliation ref="#struct-304384"/>
                </author>
                <author role="aut">
                  <persName>
                    <forename type="first">Sébastien</forename>
                    <surname>Goeb</surname>
                  </persName>
                  <email type="md5">3a5b95f3d43ce9922484245a78c22792</email>
                  <email type="domain">univ-angers.fr</email>
                  <idno type="idhal" notation="string">sgoeb</idno>
                  <idno type="idhal" notation="numeric">176197</idno>
                  <idno type="halauthorid" notation="string">31859-176197</idno>
                  <idno type="ORCID">https://orcid.org/0000-0003-2470-0768</idno>
                  <idno type="IDREF">https://www.idref.fr/118654667</idno>
                  <affiliation ref="#struct-213131"/>
                </author>
                <author role="aut">
                  <persName>
                    <forename type="first">Marc</forename>
                    <surname>Sallé</surname>
                  </persName>
                  <email type="md5">c2c9a4bd6f3469d0a452e9b6e8627277</email>
                  <email type="domain">univ-angers.fr</email>
                  <idno type="idhal" notation="string">marc-salle</idno>
                  <idno type="idhal" notation="numeric">183386</idno>
                  <idno type="halauthorid" notation="string">28631-183386</idno>
                  <idno type="ORCID">https://orcid.org/0000-0003-4601-6334</idno>
                  <idno type="IDREF">https://www.idref.fr/09085697X</idno>
                  <affiliation ref="#struct-213131"/>
                </author>
              </analytic>
              <monogr>
                <idno type="halJournalId" status="VALID">129712</idno>
                <idno type="issn">2304-6740</idno>
                <title level="j">Inorganics</title>
                <imprint>
                  <publisher>MDPI AG</publisher>
                  <biblScope unit="volume">6</biblScope>
                  <biblScope unit="issue">2</biblScope>
                  <biblScope unit="pp">44</biblScope>
                  <date type="datePub">2018</date>
                </imprint>
              </monogr>
              <idno type="doi">10.3390/inorganics6020044</idno>
              <idno type="okina">ua17928</idno>
              <ref type="publisher">https://www.mdpi.com/2304-6740/6/2/44</ref>
            </biblStruct>
          </sourceDesc>
          <profileDesc>
            <langUsage>
              <language ident="en">English</language>
            </langUsage>
            <textClass>
              <keywords scheme="author">
                <term xml:lang="en">supramolecular chemistry</term>
                <term xml:lang="en">self-assembly</term>
                <term xml:lang="en">redox-active compound</term>
                <term xml:lang="en">metalla-macrocycle</term>
                <term xml:lang="en">coordination compound</term>
                <term xml:lang="en">9-(1</term>
                <term xml:lang="en">3-dithiol-2-ylidene)Fluorene</term>
              </keywords>
              <classCode scheme="halDomain" n="chim">Chemical Sciences</classCode>
              <classCode scheme="halTypology" n="ART">Journal articles</classCode>
              <classCode scheme="halOldTypology" n="ART">Journal articles</classCode>
              <classCode scheme="halTreeTypology" n="ART">Journal articles</classCode>
            </textClass>
            <abstract xml:lang="en">
              <p>A redox-active M2L2 metalla-macrocycle is depicted, of which construction has been achieved through coordination driven self-assembly from an electron-rich 9-(1,3-dithiol-2-ylidene)fluorene bis-pyridyl ligand and a cis-blocked square planar palladium complex (Pd(dppf)OTf2, dppf = 1,1′-Bis(diphenylphosphino)ferrocene). The resulting metalla-macrocycle has been fully characterized in solution, as well as in the solid state (X-ray crystal structure). Its electronic properties show that both constitutive ligands can be oxidized independently through a one-electron process.</p>
            </abstract>
          </profileDesc>
        </biblFull>
      </listBibl>
    </body>
    <back>
      <listOrg type="structures">
        <org type="laboratory" xml:id="struct-213131" status="VALID">
          <idno type="ISNI">0000000122880078</idno>
          <idno type="RNSR">200411667U</idno>
          <idno type="ROR">https://ror.org/039yyx623</idno>
          <orgName>MOLTECH-Anjou</orgName>
          <date type="start">2004-01-01</date>
          <desc>
            <address>
              <addrLine>MOLTECH-Anjou UMR 6200 CNRS - Université d'Angers, Faculté des Sciences, 2 Boulevard Lavoisier, Bâtiments K et Db - 49045 Angers CEDEX 01</addrLine>
              <country key="FR"/>
            </address>
            <ref type="url">http://moltech-anjou.univ-angers.fr/</ref>
          </desc>
          <listRelation>
            <relation name="UMR6200" active="#struct-74911" type="direct"/>
            <relation active="#struct-341038" type="direct"/>
            <relation name="UMR6200" active="#struct-441569" type="direct"/>
          </listRelation>
        </org>
        <org type="laboratory" xml:id="struct-439404" status="VALID">
          <idno type="IdRef">176148825</idno>
          <idno type="RNSR">201019679B</idno>
          <idno type="IdUnivLorraine">[UL]RPI--</idno>
          <idno type="ROR">https://ror.org/05yc49b49</idno>
          <orgName>Laboratoire de Chimie et Physique - Approche Multi-échelle des Milieux Complexes</orgName>
          <orgName type="acronym">LCP-A2MC</orgName>
          <date type="start">2012-01-01</date>
          <desc>
            <address>
              <addrLine>Université de Lorraine, ICPM, 1 boulevard Arago, CP 87811, 57078 Metz Cedex 3</addrLine>
              <country key="FR"/>
            </address>
            <ref type="url">http://lcp-a2mc.univ-lorraine.fr/</ref>
          </desc>
          <listRelation>
            <relation name="UR4632" active="#struct-413289" type="direct"/>
          </listRelation>
        </org>
        <org type="institution" xml:id="struct-304384" status="VALID">
          <idno type="ROR">https://ror.org/02aaqv166</idno>
          <orgName>Taras Shevchenko National University of Kyiv</orgName>
          <desc>
            <address>
              <addrLine>64/13, Volodymyrska Street, City of Kyiv, Ukraine, 01601</addrLine>
              <country key="UA"/>
            </address>
            <ref type="url">http://www.knu.ua/en/</ref>
          </desc>
        </org>
        <org type="institution" xml:id="struct-74911" status="VALID">
          <idno type="IdRef">026402920</idno>
          <idno type="ISNI">0000000122483363</idno>
          <idno type="ROR">https://ror.org/04yrqp957</idno>
          <orgName>Université d'Angers</orgName>
          <orgName type="acronym">UA</orgName>
          <date type="start">1971-10-25</date>
          <desc>
            <address>
              <addrLine>Université d'Angers - 40 Rue de Rennes, BP 73532 - 49035 Angers CEDEX 01</addrLine>
              <country key="FR"/>
            </address>
            <ref type="url">http://www.univ-angers.fr/</ref>
          </desc>
        </org>
        <org type="institution" xml:id="struct-341038" status="VALID">
          <idno type="IdRef">232435103</idno>
          <idno type="ISNI">000000010626358X</idno>
          <idno type="ROR">https://ror.org/02cte4b68</idno>
          <orgName>Institut de Chimie - CNRS Chimie</orgName>
          <orgName type="acronym">INC-CNRS</orgName>
          <date type="start">2009-10-01</date>
          <desc>
            <address>
              <addrLine>CENTRE NATIONAL DE LA RECHERCHE SCIENTIFIQUE3 rue Michel-Ange75794 PARIS CEDEX 16 - France</addrLine>
              <country key="FR"/>
            </address>
            <ref type="url">http://www.cnrs.fr/inc</ref>
          </desc>
        </org>
        <org type="regroupinstitution" xml:id="struct-441569" status="VALID">
          <idno type="IdRef">02636817X</idno>
          <idno type="ISNI">0000000122597504</idno>
          <idno type="ROR">https://ror.org/02feahw73</idno>
          <orgName>Centre National de la Recherche Scientifique</orgName>
          <orgName type="acronym">CNRS</orgName>
          <date type="start">1939-10-19</date>
          <desc>
            <address>
              <country key="FR"/>
            </address>
            <ref type="url">https://www.cnrs.fr/</ref>
          </desc>
        </org>
        <org type="institution" xml:id="struct-413289" status="VALID">
          <idno type="IdRef">157040569</idno>
          <idno type="IdUnivLorraine">[UL]100--</idno>
          <idno type="ROR">https://ror.org/04vfs2w97</idno>
          <orgName>Université de Lorraine</orgName>
          <orgName type="acronym">UL</orgName>
          <date type="start">2012-01-01</date>
          <desc>
            <address>
              <addrLine>34 cours Léopold - CS 25233 - 54052 Nancy cedex</addrLine>
              <country key="FR"/>
            </address>
            <ref type="url">http://www.univ-lorraine.fr/</ref>
          </desc>
        </org>
      </listOrg>
      <listOrg type="projects">
        <org type="anrProject" xml:id="projanr-40813" status="VALID">
          <idno type="anr">ANR-14-CE08-0001</idno>
          <idno type="program">Appel à projets générique</idno>
          <orgName>BOMBER</orgName>
          <desc>Largage contrôlé d'invités par des cages auto-assemblées électro-actives</desc>
          <date type="start">2014</date>
        </org>
      </listOrg>
    </back>
  </text>
</TEI>