Mechanofluorochromic and thermochromic properties of simple tetraphenylethylene derivatives with fused fluorine containing 1,4-dioxocane rings - Archive ouverte HAL Accéder directement au contenu
Article Dans Une Revue Dyes and Pigments Année : 2017

Mechanofluorochromic and thermochromic properties of simple tetraphenylethylene derivatives with fused fluorine containing 1,4-dioxocane rings

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Hongxiang Wu
  • Fonction : Auteur
Yue Jiang
  • Fonction : Auteur
  • PersonId : 992294
Yang Ding
  • Fonction : Auteur
  • PersonId : 763914
  • IdRef : 164843396
Yuying Meng
  • Fonction : Auteur
Zhuo Zeng
  • Fonction : Auteur
Clément Cabanetos
Guofu Zhou
  • Fonction : Auteur
Jinwei Gao
  • Fonction : Auteur
Jean Roncali

Résumé

A series of tetraphenylethylenes (TPE) derivatives in which one or more of the phenyl rings have been replaced by a fused fluorine containing 2,3,4,5-tetrahydrobenzo[b][1,4]dioxocane unit have been synthesized. The analysis of the photoluminescence emission under application of mechanical grinding and thermal treatment show that in addition to the expected aggregation induced emission behavior observed in solution, these simple modifications of the TPE system confer mechanofluorochromic properties to the corresponding materials. The results of X-ray diffraction and theoretical calculations suggest that the introduction of tetrafluorobutylenedioxy “loops” control the balance between weak intermolecular interactions and thus the interconversion between “macro” and “micro-aggregates” which is proposed as the basic mechanism for the observed MFC properties.

Domaines

Chimie
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Dates et versions

hal-02564500 , version 1 (05-05-2020)

Identifiants

Citer

Hongxiang Wu, Yue Jiang, Yang Ding, Yuying Meng, Zhuo Zeng, et al.. Mechanofluorochromic and thermochromic properties of simple tetraphenylethylene derivatives with fused fluorine containing 1,4-dioxocane rings. Dyes and Pigments, 2017, 146, pp.323-330. ⟨10.1016/j.dyepig.2017.07.026⟩. ⟨hal-02564500⟩
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