Evaluation of Plasmonic Optical Heating by Thermal Lens Spectroscopy
Résumé
This work reveals the rules of using figures of merit on selecting efficient plasmonic nanoheaters. Here, a size dependence of
plasmonic nanoparticle optical heating was disclosed. The continuous laser heating of gold nanospheres is evaluated exploring a theoretical approach and thermal lens spectroscopy, which allowed identifying micro-degree temperature changes of
laser heated colloidal gold nanospheres of varying sizes. Our findings indicate that the temperature of photoheating colloidal
particles rises according to the Joule number values. The optimal gold nanospheres diameter for efficient colloidal laser
heating was identified to be 50 nm. Moreover, we demonstrated that long-time domain measurements of colloidal sample
enable the identification of single-particle intermediate steady-state temperature. Considering a single particle, nanospheres
with diameter larger than 80 nm exhibit superior heating performance than smaller particles, revealing that the optimal particle size for single-particle optical heating applications is different from the optimal particle size for collective heating of
nanoparticles. Our results pave the way for the rational use of plasmonic nanoheaters in photothermal applications.
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